What is electrochemical series and its applications. Define Electrochemical Series. Write Its Applications 2022-11-16

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An electrochemical series is a list of elements arranged in order of their standard electrode potentials. Standard electrode potential, also known as reduction potential, is a measure of the tendency of an element to be reduced (gain electrons) in a chemical reaction. It is typically measured in volts and is represented by the symbol EĀ°. A negative EĀ° value indicates a high tendency to be reduced, while a positive EĀ° value indicates a low tendency to be reduced.

The electrochemical series is useful in predicting the direction of a redox (reduction-oxidation) reaction. A redox reaction is a chemical reaction in which one element is reduced (gains electrons) while another element is oxidized (loses electrons). The element with the more positive EĀ° value will be the reducing agent, while the element with the more negative EĀ° value will be the oxidizing agent.

For example, consider the reaction between zinc and copper:

Zn(s) + Cu2+(aq) ā†’ Zn2+(aq) + Cu(s)

In this reaction, zinc is being reduced (gaining electrons) while copper is being oxidized (losing electrons). According to the electrochemical series, zinc has a more negative EĀ° value than copper, so it is the reducing agent. Copper, on the other hand, has a more positive EĀ° value, making it the oxidizing agent.

The electrochemical series is also useful in predicting the feasibility of a redox reaction. If the difference in EĀ° values between the reactants is large, the reaction is more likely to occur. If the difference is small, the reaction is less likely to occur.

There are many practical applications of the electrochemical series. One common application is in the field of electroplating, in which a thin layer of one metal is deposited onto the surface of another metal using an electric current. The metal to be electroplated (the cathode) is placed in a solution containing ions of the metal to be deposited (the anode). By using the electrochemical series, it is possible to predict which metals can be electroplated onto which other metals.

Another application of the electrochemical series is in the field of batteries and fuel cells. In a battery, a chemical reaction occurs that releases electrical energy. The electrochemical series can be used to predict which elements will be the most effective at releasing electrical energy and which elements will be the most effective at storing electrical energy. In a fuel cell, a chemical reaction occurs that releases electrical energy and produces water as a byproduct. The electrochemical series can be used to predict which elements will be the most effective at releasing electrical energy and producing water.

In summary, the electrochemical series is a list of elements arranged in order of their standard electrode potentials. It is useful in predicting the direction and feasibility of redox reactions and has many practical applications, including in electroplating, batteries, and fuel cells.

Electrochemical Series

what is electrochemical series and its applications

A More Hydrogen gas is evolved. The oxides of metals having high positive reduction potentials are not stable towards heat. This means that zinc is a better reducing agent than hydrogen and is more easily oxidised. Applications of Electrochemical Series: For Choosing Elements as Oxidising Agents: The elements which have more electron-accepting tendency are oxidizing agents. Such element is called oxidizing agent as in the process of gaining electron or electrons it is oxidizing other element which is losing electron easily.

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Define electrochemical series and write its applications?

what is electrochemical series and its applications

Metals like Cu, Hg and Ag placed in this group. The reaction must be occurring in the reverse direction. F 2 is the strongest oxidizing agent. EMF series is defined as the arrangement of the electrode with the electrode half-reaction in order of decreasing standard potentials. For Studying displacement reaction: One metal can be displaced from a salt solution by another metal is known as a redox reaction. Electrochemical series Amassing the standard electrode potentials of different elements creates the electrochemical series.

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Electrochemical Series and its Important Applications

what is electrochemical series and its applications

In contrast to this, in the case of nonmetals, a nonmetal with higher reduction potential can displace the nonmetal with low reduction potential. The electrochemical series of halfā€”cell reaction potentials, can be used to predict which ions are likely to be preferentially discharged to form electrolysis products on the cathode + pole in electrolysis or anode + pole in electrolysis. Hence Fe can easily displace copper from CuSO 4. If the emf is negative then the reaction will not occur. All the substances appearing at the bottom of the table are good oxidizing agents. It means the metal placed above the electrochemical series can displaced the metal from its solution which is placed below it.

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Electrochemical series and its applications

what is electrochemical series and its applications

What are the applications of electrochemical series or electromotive series? For example, a Alkali metals and alkaline earth metals having high negative values of standard reduction potentials are chemically active. To Determine the Products of Electrolysis: In case two or more types of positive and negative ions are present in solution, during electrolysis certain ions are discharged or liberated at the electrodes in preference to others. Thus, the metals having - EĀ° values liberate hydrogen from acids. This means that we write the ions and electrons on the left-hand side and the combined element on the right-hand side. This creates a potential difference between the zinc rod and the zinc ion solution, known as an electrode potential.

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electrochemical series and its applications Archives

what is electrochemical series and its applications

. This is because in e. The negative sign of standard electrode potential of a metal showed that when this metal electrode is combined with hydrogen electrode it act as anode and oxidation reaction takes place at this electrode. SHE has the middle position in the electrochemical series. In order to understand the electrochemical series and how they arranged, first, we will consider the explanation of some other terminologies. These various electrodes can be arranged in increasing or decreasing order of their reduction potentials. From the electrochemical series, we can predict the feasibility of the reaction, the emf of the cell, and the formation of hydrogen gas from dilute mineral acid by metal, etc.

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Electrochemical Series: Explanation & Table

what is electrochemical series and its applications

We can use this to generate electricity. The electrode potential having a high reduction potential value is found to be less reactive. They can react with cold water and evolve hydrogen. The Electrochemical Series:The electrochemical series is an arrangement of metals based on the tendency of each metal atom to donate electrons. Helps in predicting liberation of hydrogen gas from acids by metals. It tells us how easily each element is oxidised compared to a reference half-cell, the hydrogen electrode.

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What is electrochemical series and its uses?

what is electrochemical series and its applications

However, we can measure the potential difference generated when you connect two half-cells together in an In fact, scientists have done this. So they are good oxidizing agents. Created by comparing different electrode potentials to conventional hydrogen electrodes, the electrochemical series helps in the arrangement of components. The element on the top the series is a strongest reducing agent which means it can lose electron easily than any other element and it is also most active metal. So in the process of oxidation it reduces the other element so it is called reducing agent. In general, a redox reaction is feasible only if the species which has a higher reduction potential is reduced i. Electrochemical series table The moment you've been waiting for - here's the electrochemical series.

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Define Electrochemical Series. Write Its Applications

what is electrochemical series and its applications

Displacement of hydrogen from dilute acids by metals: The metal which can provide electrons to H + ions present in dilute acids for reduction evolve hydrogen from dilute acids. In general, species with a negative electrode potential are good reducing agents and tend to lose electrons themselves. Applications Electrochemical series can be used to predict various properties of an element based on their position in the series relative to the hydrogen electrode. It is a measurement of the element's reducing ability. Among Zinc and copper, copper acts as a cathode whereas Zinc acts as an anode as copper has a higher reduction potential.

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Electrochemical series

what is electrochemical series and its applications

So the alkali metals and alkaline earth metals are classified as strong electropositive metals. As we move down in the series activity and electropositivity of metals increase. Essentials of physical chemistry. We call the potential difference between a half-cell and the reference hydrogen electrode under standard conditions the cell's standard electrode potential. So bottom elements in electrochemical series are reducing agents.

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